Solid-State Inorganic Chemistry

Crystal structures, defects, and the thermochemistry of extended solids.


foundation tier

Solid-State Inorganic Chemistry — Crystal structures, defects, and the thermochemistry of extended solids.

The field organises around several methodological axes: how the underlying objects are modelled, how they are measured, how they are connected to the rest of chemistry, and which empirical phenomena drive open questions. The references below anchor the topic in established treatments and current literature.

Foundations and core methods

A primary reference for this area is Solid State Chemistry and its Applications (West, 2014), which lays out the core concepts that govern solid-state inorganic chemistry. The treatment frames the subject within the broader context of inorganic chemistry and motivates the conceptual vocabulary used throughout this page. The discussion here cites this work as a general anchor rather than for a specific claim, since the exact contribution claim is treated cautiously in line with the Charted sourcing policy.

A complementary perspective comes from Solid State Chemistry: An Introduction (Smart and Moore, 2005), which provides further background on the methods and results most relevant to solid-state inorganic chemistry. Together with the previous reference, it establishes the standard expectations for how practitioners approach the topic in current practice.

Current developments

More recent or specialised work appears in New Directions in Solid State Chemistry (Rao and Gopalakrishnan, 1986), which we cite here as a general entry point to that direction; specific quantitative claims about its contribution are not made.

Open questions

Open methodological questions in solid-state inorganic chemistry include the transferability of the standard methods to harder regimes, the integration of newer measurement and modelling tools, and the connection to neighbouring subfields of inorganic chemistry. Future revisions of this page will deepen the treatment as more primary literature is curated.

Prerequisites

Sources

  • textbook · primary · 2014
    Solid State Chemistry and its Applications
    west-anthony-2014
  • textbook · primary · 2005
    Solid State Chemistry: An Introduction
    smart-2005, moore-2005
  • textbook · historical · 1986
    New Directions in Solid State Chemistry
    rao-1986, gopalakrishnan-1986

In context

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Explore

  1. 01

    Inorganic Crystal Structures

    Close packings, common structure types (rocksalt, fluorite, perovskite, spinel), and Pauling rules.

  2. 02

    Defects and Nonstoichiometry

    Point and extended defects, Frenkel/Schottky, and their effect on properties.

  3. 03

    Solid-State Synthesis Methods

    High-temperature, flux, sol–gel, and topochemical routes to extended solids.

  4. 04

    Intercalation Chemistry

    Insertion and removal of guest ions in layered hosts — graphite, transition-metal dichalcogenides, oxides.

  5. 05

    Zeolites and Microporous Solids

    Crystalline aluminosilicates and related microporous frameworks — synthesis, structure, and catalysis.


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