Surface and Interface Chemistry

Chemistry at the boundaries between phases — adsorption, wetting, and surface reactions.


field tier

Surface and Interface Chemistry — Chemistry at the boundaries between phases — adsorption, wetting, and surface reactions.

The field organises around several methodological axes: how the underlying objects are modelled, how they are measured, how they are connected to the rest of chemistry, and which empirical phenomena drive open questions. The references below anchor the topic in established treatments and current literature.

Foundations and core methods

A primary reference for this area is Introduction to Surface Chemistry and Catalysis (Somorjai and Li, 2010), which lays out the core concepts that govern surface and interface chemistry. The treatment frames the subject within the broader context of chemistry and motivates the conceptual vocabulary used throughout this page. The discussion here cites this work as a general anchor rather than for a specific claim, since the exact contribution claim is treated cautiously in line with the Charted sourcing policy.

A complementary perspective comes from Physical Chemistry of Surfaces (Adamson and Gast, 1997), which provides further background on the methods and results most relevant to surface and interface chemistry. Together with the previous reference, it establishes the standard expectations for how practitioners approach the topic in current practice.

Open questions

Open methodological questions in surface and interface chemistry include the transferability of the standard methods to harder regimes, the integration of newer measurement and modelling tools, and the connection to neighbouring subfields of chemistry. Future revisions of this page will deepen the treatment as more primary literature is curated.

Prerequisites

Sources

  • textbook · primary · 2010
    Introduction to Surface Chemistry and Catalysis
    somorjai-2010, li-yimin-2010
  • textbook · primary · 1997
    Physical Chemistry of Surfaces
    adamson-1997, gast-1997

In context

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Explore

  1. 01

    Adsorption Theory

    Langmuir, BET, and Freundlich isotherms; physisorption and chemisorption.

  2. 02

    Surface Spectroscopies

    XPS, AES, UPS, and HREELS for surface composition and electronic structure.

  3. 03

    Self-Assembled Monolayers

    Thiol-on-gold and silane SAMs — structure, functional design, and applications.

  4. 04

    Atomic Layer Deposition

    Self-limiting surface reactions for conformal thin films at the atomic scale.

  5. 05

    Wetting and Contact-Angle Chemistry

    Surface energies, super-hydrophobic surfaces, and capillary phenomena.

  6. 06

    Electrochemical Interfaces

    Electric double layer, Helmholtz/Gouy–Chapman/Stern models, and interfacial spectroscopy.

  7. 07

    Colloidal Chemistry

    DLVO theory, colloidal stability, and engineered colloidal suspensions.

  8. 08

    Emulsion and Foam Chemistry

    Surfactants, microemulsions, Pickering emulsions, and stabilization mechanisms.

  9. 09

    Corrosion Chemistry

    Electrochemistry of metal corrosion and the design of inhibitors and protective coatings.


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